Latest paper

22 Novembre 2018: Our latest results on the controlled release of carbon monoxide (the silent killer gas) from organometallic complexes is now online (and open access)

Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex published in ACS Omega

A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO(g). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.

Topics: Acylation; Coordination chemistry (Organomet.); Equilibrium constant; Free energy

Welcome! and Congratulations

4 September 2018: Delighted to welcome Maria in the group; this time as a PhD student! Things are getting serious and exciting.

Maria

With a bit of delay (Aug 3, 2018), also very happy to welcome Joan, arriving fresh from Bochum to work with us on an Academy of Medical Sciences funded project.

IMG_0931

And since we are catching up on the news section, congrats to Nicolas on meeting the requirements for Fellowship of The Higher Education Academy. Next in line is Anaïs (expected 2019). Good luck to her!